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    Valencian red imprimaturs since Francisco Ribalta (1565–1628)

    Autor: 
    Castelló-Palacios, Amparo
    ;
    Montoya, Noemí
    ;
    Doménech-Carbó, Antonio
    ;
    Guerola-Blay, Vicente
    ;
    Pérez-Marín, Eva
    ;
    Doménech-Carbó, María Teresa
    Fecha: 
    2022
    Palabra clave: 
    FESEM-EDX; mars red, imprimatur; microraman spectroscopy; oil painting; red lake; valencian painting; Scopus; JCR
    Revista / editorial: 
    Elsevier Masson s.r.l.
    Tipo de Ítem: 
    article
    URI: 
    https://reunir.unir.net/handle/123456789/13270
    DOI: 
    https://doi.org/10.1016/j.culher.2021.11.010
    Dirección web: 
    https://www.sciencedirect.com/science/article/pii/S1296207421001825?via%3Dihub
    Open Access
    Resumen:
    The aim of this study was to confirm the use of an admixture of natural earth and a second unusual Al-rich red pigment in the imprimaturs of paintings that date back to 1600–1660, painted by some of the most outstanding Valencian Baroque painters. For this purpose, microsamples excised from six paintings were prepared as cross-sections to be analysed by optical microscopy (OM) and field emission scanning electron microscopy-X-ray microanalysis (FESEM-EDX) combined with Fourier Transform Infrared (FTIR) spectroscopy, microRaman spectroscopy and voltammetry of immobilized microparticles (VIMP). Two possible red pigments, red lake or synthetic Mars red could be used by these painters in red imprimaturs mixed with natural earth pigments. This particular technique, identified for the first time in seventeenth-century Valencian paintings of known authorship, is a novel finding than can help in authentication studies of unknown Baroque paintings.
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